April 2025

Coating A-Z: A for Aging of Adhesives and Bonding

Sun, rain, heat, and cold – our environment leaves its marks not only on buildings but also on outdoor advertising graphics. Anyone who has ever seen a faded or peeling film on a windowpane has experienced the effects of these environmental influences firsthand.

The aging of materials is an unavoidable process that affects not only biological systems but also technical materials such as plastics and adhesives. Since aging effects are often not immediately visible, it is essential to analyze the relevant influencing factors and develop methods for experimental simulation. These tests are conducted to determine the durability of films used in graphic applications, such as advertising on storefronts. This allows for early detection of how long such materials can maintain their optical and mechanical integrity under various environmental conditions. These tests help predict the long-term stability of adhesive bonds under environmental influences such as temperature, humidity, UV radiation, and mechanical stress—an important quality factor for high-performance self-adhesive media.

 

Factors Influencing the Aging of Adhesives

The aging of adhesives and bonded joints is influenced by a variety of external factors. The most important degradation mechanisms include:

  1. Temperature: Elevated temperatures accelerate chemical and physical processes that can lead to material fatigue.
  2. Humidity: Water and high humidity can trigger hydrolysis processes—chemical reactions in which a compound is broken down by water. In adhesives, this means that moisture can degrade polymer chains, which may impair the mechanical properties of the adhesive bond by reducing adhesion or causing the material to become brittle.
  3. Radiation: Both visible light and UV radiation can cause photochemical degradation, breaking down polymer chains and reducing adhesive effectiveness.
  4. Mechanical stress: Wind, tensile, or compressive loads can lead to material fatigue and compromise the integrity of adhesive bonds.

In general, any form of energy exposure accelerates aging processes and can shorten the lifespan of adhesive systems.

 

Experimental Simulation of Aging

To predict the service life of adhesives and bonded joints, targeted aging tests are conducted in laboratory environments. These tests accelerate real-world conditions to obtain reliable results within a short period. The most important test methods include:

  • UV and light aging tests: Specialized radiation chambers expose adhesive bonds to high-intensity UV and visible light to analyze photochemical aging effects.
  • Climate chambers: Alternating temperature and humidity conditions (e.g., summer-winter or day-night cycles) simulate long-term environmental influences.
  • Mechanical stress tests: Cyclic tensile, compressive, and shear loads are applied to evaluate material fatigue.

 

Conclusion

The aging of adhesives and bonded joints is a complex process influenced by numerous factors. However, targeted laboratory investigations allow for realistic predictions about the durability of adhesive systems and, consequently, of self-adhesive media used in applications such as graphic advertising.